NFPA Hazard Ratings:

•  Manganese 2-Ethylhexanoate

• Manganese Neodecanoate

• Manganese Stearate

Emergency Overview: Caution: Eye and respiratory irritant.

Potential Health Effects:

• Signs and Symptoms of Acute Overexposure: Eye, respiratory irritation, dizziness, fatigue, headache, unconsciousness or asphyxiation.
• Signs and Symptoms of Chronic overexposure: Dermatitis and defatting of skin
• Medical Conditions Generally Aggravated by Exposure: Allergies, chronic asthma may be exacerbated by fumes from this product..
• Ingestion: Irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion.

• Inhalation: Remove victim to fresh air. If breathing is impaired, administer oxygen. Keep patient warm and quie.t
• Ingestion: Do not induce vomiting. Give patient 2 - 4 glasses of water or milk to drink to dilute the product. Get medical advice.
• Skin Contact: Remove contaminated clothing and footwear. Wash skin with soap and water. Wash clothing before reuse.
• Eye Contact: Immediately flush eyes with water for 15 minutes. Get medical attention.
• Note to Physician: None

 Flash Point: 145 degrees F

Flammability Limits: NA

Autoignition temp: NA

Fire Extinguishing Media: Foam, water fog, carbon dioxide, dry chemical. Do not use a direct stream of water. Product will float and can be reignited on surface of water.

Special Fire-Fighting Information: When entering confined space, wear positive pressure NIOSH-approved SCNA, full bunker gear (helmet with face shield, bunker coats, gloves and rubber boots) Use water spray to cool containers, to prevent weakening of container structure or buildup of vapor pressure which could result in container rupture.

Unusual Fire and Explosion Hazards: Vapors are heavier than air and may travel along the ground.

Caution - combustible. Eliminate potential sources of ignition. Wear Appropriate respirator and other protective clothing. Contain spill. Remove with vacuum trucks or pump to storage/slavage vessels. Soak up residue with an absorbent such as clay, sand, or other suitable material; place in non-leaking containers and seal tightly for proper disposal. Flush area with water to remove trace residue dispose of flush solution as above.

For Small Spills: Take up with an absorbent material and place in a non-leaking container for proper disposal.

• Ventilation System: Good general ventilation is advisable
• Personal Respirators (NIOSH Approved): if needed, use respirator to screen out nuisance dust
• Skin Protection: Long sleeved clothing and oil-resistant gloves
• Eye Protection: Chemical safety goggles or face mask.
• Other Control Measures:

ACGIH (TVL) Limits: CAS 64742-88-7 -100 ppm;
OSHA PEL: CAS 64742-88-7 -100 ppm;

• Appearance and Color: Transparent dark red-brown liquid
• Odor: Aromatic odor
• Solubility in Water: Nil
• Specific Gravity: 0.8155 at 70 degrees F
• Kinematic viscosity at 100 deg. F: 3.21 cs
• Density - lbs/gal: 6.799
• pH: NA
• % volatile by volume @ 21C (70F): NDA
• Boiling Point: 400 degrees F, 100 degrees C
• Melting Point: NA
• Vapor Density (Air=1): = > 1
• Vapor Pressure (mm Hg): = < 5
• Evaporation Rate (Bu. Acetate=1): = < 1

• Stability: Product is stable under normal conditions.
• Hazardous Decomposition Products: Carbon monixide and ioxide on combustion
• Hazardous Polymerization: will not occur.
• Incompatibility: Strong oxidizers. May soften some plastics.
• Conditions to Avoid: Incompatibilites.

• Toxicological Data:

RTECS: CAS# 64742-88-7 WJ8925000/ CAS# 27253-32-3:1012164MN/ CAS# 15956-58-8:1006132ME/ CAS# 61791-24-0: KO9275000/ CAS# 64741-60-2:1008158DP

LD50 /LC50: CAS# 64791-60-2: NDA / CAS 61791-24-0: Acute oral LD50 813 mg/kg (rat)/ /CAS# 9005-07-6: Oral, rat LD50 = 692 mg/Kg / CAS# 61791-24-0: Oral, ratl LD50 = 813 mg/kg / /CAS# 15956-58-8: NDA / CAS# 27253-32-3: NDA / CAS# 3353-06-7: NDA

• Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTR, or OSHA

• Environmental Fate: NDA
• Environmental Toxicity: NDA

• DOT Proper Shipping Name: Not regulated as hazardous by DOT when packaged in drums of 120 gallons
  --------------------------------------------------------------------------------------------------------------------------
  Containers above 120 gallons:
  DOT Proper Shipping Name: Petroleum Distillates, N.O.S. (Contains Petroleum Naphtha)
  DOT Hazard Class: NA for containers of < 120 gallons, otherwise class III, Combustible liquid
  Packing Group: III
  UN CODE: 1268
  DOT Label: NA for containers of < 120 gallons, otherwise label as Environmentally Hazardous Substance, Liquid N.O.S

• TSCA: All ingredients are listed on the TSCA inventory with no special reporting regulations.
• CERCLA Reportable Quantity: Not subject to CERCLA reporting
• SARA TITLE III:

..................................Section 302/304 Extremely Hazardous Substances: None

..................................Section 311 Hazard Categorization: Acute health, chronic, delayed health, Fire

..................................Section 313 Toxic Chemicals: None

• STATE Right-To-Know Lists: Naphthalene, CAS# 91-20-3, representing 110% of this product, IS l listed on the following RTK lists: Pennsylvania, New Jersey, California & Massachusetts. Other ingredients are not listed on any of the following state RTK lists: California, Connecticut, Florida, Illinois, Louisiana, Maine, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, or Rhode Island.
• California Proposition 65 labeling requirements: This product contains the following chemicals known to the state of California to cause cancer and/or birth defects: Naphthalene, CAS# 91-20-3, representing 11% of this formula.
• CLEAN AIR ACT: This product does not contain, nor does was it directly manufactured with any class I or II ozone depleting substances.
• CLEAN WATER ACT/OIL POLLUTION ACT: This product is classified as an oil under Section 31 of the Water Act (40 CFR 110) and the Oil Pollution Act of 1990. Discharges or spills which produce a visible sheen on either surface water or waterways/sewers which lead to surface water, must be reported to the National Response Center at 800-424-8802.
• CANADA: Ingredients listed on the Domestic Substances List. Product authorized for sale in Canada..
  WHMIS classification: B3 Combustible Liquid & D2B
• Canada's Ingredient Disclosure List: Naphthalene, CAS# 91-20-3, representing 11% of this product, is listed on the CIDL. Other ingredients are NOT listed on the CiDL. This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

Reason for Revision: Routine Review & Revision

Alken-Murray Corporation provides the information contained herein in good faith, in compliance with the Occupational Safety and Health Act of 1970, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Alken-Murray warrants that this product is of merchantable quality. The implied warranty of fitness for a particular purpose is limited to the extent the products are used for the purpose or uses described on the product's label or in any written instructions or materials distributed to the buyer by Alken-Murray and is hereby disclaimed should buyer use the products in a manner inconsistent with this uses or purposes described therein. In no event shall Alken-Murray be liable for any consequential, exemplary, or incidental damages incurred by buyer even if it has been advised of the possibility of such damages.